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Posted
As for the explosion at a petrol station i think you'll find that petrol will go up very easily but you could chuck a cigarette into a bucket of diesel with no probs (at room temp). It's all to do with vaporisation at average temperatures.

 

Exactly, only more eloquently explained :)

Posted

The flash point of a liquid is the temperature at which sufficient vapour is released to allow ignition. This is pretty low for petrol (-43 °C) but this obviously does not mean that spontaneous ignition will occur at that temperature. However, it does mean that at any temperature above this, a certain amount of heat applied to even a small amount of the vapour may start the conflagration.

 

The spontaneous ignition temperature of a fuel is much higher than the flash point. For petrol it is somewhere between 200 °C and 300 °C.

Posted
Crikey localzuk, you'd be a good man to have on board in a pub quiz. Or have you got a dedicated Google terminal? I think we should be told.

 

I used to work in a petrol station and was sent on several fire training days where this lot was told to me (and the other attendees). Dunno why I remember it though!!

 

It's not the petrol that ignites, it's the vapour. I've done some quite sever fire fighting courses (including bulk fuel installations and other flammable storage areas) during my military hazmat and taker operator training, and there are quite a few myths about this type of thing. One fun task was trying to light aviation fuel with a math, lighter, candle and then blowtorch. Apart from the blow torch it was a lesson in futility. Fun days, especially firing hundreds of gallons of foam over fuel fire pits :)

 

The petrol itself can ignite too. It just requires the petrol to be heated to the autoignition temperatures I mentioned earlier. This is, as I said, unlikely in a large quantity of fuel as the fuel's temperature would cause the temperature of the cigarette to be decreased very quickly and it would be put out. However, in a thin layer of fuel, it is possible - especially if the tip of the cigarette is what touches the liquid (it is obviously hotter in the center of the tip than around the side).

 

The flash point of a liquid is the temperature at which sufficient vapour is released to allow ignition. This is pretty low for petrol (-43 °C) but this obviously does not mean that spontaneous ignition will occur at that temperature. However, it does mean that at any temperature above this, a certain amount of heat applied to even a small amount of the vapour may start the conflagration.

 

The spontaneous ignition temperature of a fuel is much higher than the flash point. For petrol it is somewhere between 200 °C and 300 °C.

 

Yep, and when you fuel your car, you'll see quite a lot of petrol vapour coming out of your tank when you fill up. Hence the risk during smoking (and any other ignition source/activity).

Posted

Those Shell drivers make me angry. I have seen at least 3 trucking companies go bust because of fuel prices recently.

 

Those Shell drivers should be thankful they actually have a job in the trade. Instead they demand more pay. Greed!

Posted
Did no one watch the mythbusters trying to ignite petrol vapour with mobiles and cigarettes? Highly Improbable is their conclusion, also their results for mobiles.

 

MythBusters Episode 2: "Cell Phone Destruction, Silicone Breasts, CD-ROM Shattering"

 

MythBusters Special 7: "Hollywood on Trial"

 

Having set petrol alight with a cigarette at a training course, I can say that 'highly improbable' is nonsense. It simply has to be a film of petrol, which is most common on a forecourt, if a cigarette were dropped. It can and does light up.

 

And as said, the vapour is also very likely to light up.

 

Trying to say it is improbable is ridiculous.

Posted

When I wuz a lad - I worked in a petrol station - no fancy training shannigans in those days - my mate was having a crafty fag at the counter and managed to set fire to the plastic waste bin...in a panic he hefted it out through the door onto the forecourt that was awash with spilt fuel. We watched the bin burn down to a nasty black blob, praying that we weren't going to be the worst fire in Coventry since the blitz :eek: - and indeed nothing caught alight.

 

On the other hand - I worked in Mine Safety too - and watching a flash fire that happens when coal dust reaches a certain level in the air is really scary - we got called to a custard factory after they had a flash fire there too - it was a right mess.

Posted
When I wuz a lad - I worked in a petrol station - no fancy training shannigans in those days - my mate was having a crafty fag at the counter and managed to set fire to the plastic waste bin...in a panic he hefted it out through the door onto the forecourt that was awash with spilt fuel. We watched the bin burn down to a nasty black blob, praying that we weren't going to be the worst fire in Coventry since the blitz :eek: - and indeed nothing caught alight.

 

On the other hand - I worked in Mine Safety too - and watching a flash fire that happens when coal dust reaches a certain level in the air is really scary - we got called to a custard factory after they had a flash fire there too - it was a right mess.

 

Yeah. I'm not saying that it will happen 100% of the time. I'm saying the possibility is higher than some people are making out. Considerably higher!

Posted

14% hey. I don't begrudge them but let no-one dare complain when the public sector unions decide enough is enough and take action to improve the wages of the lowest paid in our society!

 

Stand by for disruption in the health service, education, local authorities etc. Will make the awkwardness of a few garages running short of fuel seem minor!!! Schools closed, hospitals emergency only, no bins emptied etc......

 

One thing that no-one seems to have answered. The drivers aren't employed by Shell but by a transport company contracted to Shell. The strikers didn't picket the offices of this company but the actual refineries. I thought that secondary picketing was illegal, I seem to remember the police and courts taking very robust action against strikers engaged in this in the past! Perhaps the police/CPS/government could explain to the miners, dockworkers, steelworkers etc who were imprisoned for secondary picketing why the same action isn`t to be taken against anyone from the road transport industry!!!

 

I also suspect that if I caused disruption on motorways etc as a protest (Haulage Companies protesting about fuel prices) I would get my collar felt very quickly.

 

Double standards, surely not!!!!

Posted
14% hey. I don't begrudge them but let no-one dare complain when the public sector unions decide enough is enough and take action to improve the wages of the lowest paid in our society!

 

Uh-huh! The local gov pay campaign is going to jump on this!

Posted
Uh-huh! The local gov pay campaign is going to jump on this!

 

I just don't think unison has that much power. And they don't seem to like upsetting the labour government that they support so much.

Posted
I just don't think unison has that much power. And they don't seem to like upsetting the labour government that they support so much.

 

Well not sure if thats true, in last years pay campaign they urged us all to strike and demanded 4%. We voted to accept the 2.45% - so what can they do?

 

This year they want us to strike, we'll see what the ballot returns. Things are tougher this year so maybe the vote will be different?

Posted
They are driving a bomb. I'd say that is dangerous

 

Not as dangerous as being a frontline soldier in Afghanistan or Iraq and most soldiers out there get paid half that of tanker drivers

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