Apple Devices use Bonjour to announce themselves on the network
Bonjour is apple's name for their zeroconfing networking
Bonjour uses 224.0.0.251/252 as addresses, the router chaps will know that those addresses are non-routable so routers drop all that traffic.
That means that an AppleTV on one subnet cannot be discovered by a Ipad on another subnet. So you can't mirror your stream to the AppleTV.
Wireless vendors are scratching their heads help what do we do.
Many vendors are selectively 'bridging' bonjour broadcasts
For example Cisco will 'bridge' the appleTV broadcasts onto the user wireless subnets (check cisco.com for detail), so users can discover the TVs
OK if you just have a couple TVs but imagine a couple hundred and all the bonjour broadcasts being swamped to all vlans all users . nightmare !.
Worth noting that AppleTV wireless only uses WPA-PSK so joining it to an 802.1x proper secure network is not an option
Also your policy on the passcode for the apple tv is going to have to be strict - if you give all apple tvs the same passcode then a student learns one passcode - could stream some very interesting stuff.
I here declare I have an interest in Aruba but it does allow role based access (only allowing staff to use TVs but allowing staff to permit ad-hoc student access)
and location based access (find the tvs in the science block or on my floor only)
jc