There's nothing the school can really do, aside from banning the use of phones that will help here. Jamming signals is possible and quite easy to do, however it is highly illegal in the UK. There was a case of a school allowing pupils to hand in their phones at the start of the day and get them back at the end of the day, which gave them access in emergencies and to arrange getting picked up etc. It was then found that pupils were bringing in two phones and handing in their old one, getting full use of their shiny 3G/4G phones! At the end of the day, it is very hard to stop pupils from getting access. It just takes one to find a way around your measures then it spreads like wildfire...