Sorry, I should've been clearer.
When clicking print from the main window, the candidate info window appears and details can be entered but when clicking print from there, the standard print dialog then appears behind the main window.
I can move it out by alt+tabbing to it and alt+space to move it with the keys on a multi-monitor setup but if I have no other monitor... no dice!
I am using Win 8.1 x64 if that makes any difference.
Cheers for the quick work btw. I shall certainly push ExamWritePad to my various associates in other schools.
[EDIT] Print dialog seems to appear fine on top in Windows 10, just my Windows 8.1. Have tried on multiple comps.