No software solution running on the PC is ever going to be able to monitor the actual power usage of the PC.
Firstly, you can only ever monitor this on the "mains plug" side of the power supply to do it accurately and take into account the relative efficiency/loss of the PSU itself.
Secondly, it would be impossible for the software to monitor how much power it was using whilst in standby, hibernation or sleep when it actually IS in standby, hibernation or sleep.
Thirdly, the constant polling/monitoring of any such software might keep the PC "active" so it can't ever become idle and drop into standby, hibernation or sleep.
The simplest, lowest-tech option is to buy a small power meter (£10 quid from Maplin) and monitor devices throughout the day, or just reset the kWh counter at the start of the week and measure it again at the end of the week.
I would also suggest connecting the power meter to a two-way, four-way or six-way extension lead so that you can measure it with a CRT/TFT monitor if required, or measure small groups of devices together (for a more accurate average).
Once you have got the calculations you can use the advanced carbon calculator linked in this post:
http://www.edugeek.net/forums/green-computing/71862-decent-carbon-calculator.html
...to work out energy used/wasted by Cost, kWh and Metric Tonnes of carbon (for CRC or CSR purposes).
Once you have done this you need to add on another 1Watt for every 3Watts of computer usages to account for any cooling/aircon required to remove the heat (if you actually have aircon that is). This is based on an assumption that most aircon units operate at 300% efficiency (which several air-con engineers have confirmed to me as a good rule-of-thumb)
Anyhow..What are you going to use the figures for once you have them?
JasonM