We are using Active Directory. I am not sure what you mean by access OWA using the name space. The users need/want to access their email by clicking on a link without entering in their username and password again. The users authenticated to Active Directory but I only have access to the userid of and not the password and they are not authenticated to the network. The system that collected the password is not passing the password to me and I can not get it. All I can get is an encrypted Active Directory userid.
I have created other SAML and SSO applications where as a programmer I have been able to connect to the outside source as what ever user I want because there was a trust built in with the Certificate used for all users to encrypt the SAML token. Only through my program I could, users could not get around it. I built the SAML 1.1, 2.0 and passed it to the other system.
I hope that this clarifies why and what I want to do.