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Posted
Anyone else having problems with users accessing OneDrive from Office? OneDrive seamlessly logs them on at log on, it shows up in File Explorer, can be navigated to online, but when trying to save a Word document to One Drive they get prompted to log on, and then get told their school address isn't recognised as a Microsoft account. Strangely, it's not affecting everyone.
Posted
I think I have things a bit clearer now - we have an internal and public domain, called, for example domainA. A few years ago the powers to be decided that @DomAinA wasn't a nice e-mail address, and told us to change it to @DomAinB. We created the new domain, registered it with 365, and all new users since then have been given the e-mail address @DomAinB. At the same time, all new accounts have the username @DomAinB. We have ADFS, and they are seamlessly logged onto 365. However, it appears that all users without a @DomAinA address aren't seamlessly connecting to OneDrive from Office. I'm sure it's something simple, and it's strange it's taken 2 years for anyone to notice, but has anyone got any ideas what I've missed?
Posted

Yep.

 

MS constantly ask for 'email address' but they actually mean UserPrincipalName. Did you change the users userprincipalname too? This is the right thing to do, but be aware doing so breaks sync for those users, and also the onedrive client (all office products) need their profile re-set-up.

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